a) \(n_{Al}=\dfrac{0,54}{27}=0,02\left(mol\right)\)

PTHH: 2Al + 6HCl --> 2AlCl₃ + 3H₂

_____0,02->0,06---->0,02--->0,03

=> V_H2 = 0,03.22,4 = 0,672 (l)

b) m_HCl = 0,06.36,5 = 2,19 (g)

=> \(C\%_{ddHCl}=\dfrac{2,19}{100}.100\%=2,19\%\)

`a)`

`2Al+6HCl->2AlCl_3+3H_2`

`n_{Al}={0,54}/{27}=0,02(mol)`

`n_{H_2}=3/{2}n_{Al}=0,03(mol)`

`V_{H_2}=0,03.22,4=0,672(l)`

`b)`

`n_{HCl}=2n_{H_2}=0,06(mol)`

`C%_{HCl}={0,06.36,5}/{100}.100%=2,19%`

2CH3COOH+Zn->(CH3COO)2Zn+H2

0,074-------------------------0,037----0,037

n (CH3COO)2Zn=0,037 mol

=>CM =\(\dfrac{0,074}{0,025}\)=3M

=>VH2=0,037.22,4=0,8288l

2CH3COOH + Zn -- > (CH3COOH)2Zn + H2

nH2 = 2,24 / 22,4 = 0,1 (mol)

=> nCH3COOH = 0,2 (mol)

mZn = 0,1. 65 = 6,5 (g)

mH2 = 0,1.2 = 0,2 (g)

mdd  = 300 + 6,5 - 0,2 = 306,3 (g)

mCH3COOH = 0,2 . 60 = 12 (g)

=> C%CH3COOH = ( 12.100 ) / 306,3 = 4%

m(CH3COO)2Zn = 0,1 . 183 = 18,3 (g)

=> (18,3.100) / 306,3 = 6%

2CH3COOH+Mg->(CH3COO)2Mg+H2

0,02---------------0,01-------0,01----------0,01

n muối=0,01mol

=>CM=\(\dfrac{0,02}{0,04}=0,5M\)

=>VH2=0,01.22,4=0,224l

CH3COOH+NaOH->CH3COONa+H2O

0,02--------------0,02

=>VNaOH=\(\dfrac{0,02}{0,75}=0,03l\)

a) \(n_{\left(CH_3COO\right)_2Mg}=\dfrac{1,42}{142}=0,01\left(mol\right)\)

PTHH: Mg + 2CH₃COOH --> (CH₃COO)₂Mg + H₂

           0,01<-------0,02<------------0,01------->0,01

=> \(C_{M\left(dd.CH_3COOH\right)}=\dfrac{0,02}{0,04}=0,5M\)

b) V_H2 = 0,01.22,4 = 0,224 (l)

c) 

PTHH: NaOH + CH₃COOH --> CH₃COONa + H₂O

             0,02<------0,02

=> \(V_{dd.NaOH}=\dfrac{0,02}{0,75}=\dfrac{2}{75}\left(l\right)=\dfrac{80}{3}\left(ml\right)\)

\(a.2CH_3COOH+Mg\rightarrow\left(CH_3COO\right)_2Mg+H_2\\ n_{\left(CH_3COO\right)_2Mg}=0,01\left(mol\right)\\ n_{CH_3COOH}=2n_{\left(CH_3COO\right)_2Mg}=0,02\left(mol\right)\\ \Rightarrow CM_{CH_3COOH}=\dfrac{0,02}{0,04}=0,5M\\ b.n_{H_2}=n_{\left(CH_3COO\right)_2Mg}=0,01\left(mol\right)\\ \Rightarrow V_{H_2}=0,01.22,4=0,224\left(l\right)\\ c.CH_3COOH+NaOH\rightarrow CH_3COONa+H_2O\\ n_{CH_3COOH}=n_{NaOH}=0,02\left(mol\right)\\ \Rightarrow V_{NaOH}=\dfrac{0,02}{0,75}=0,02667\left(l\right)=26,67ml\)

Rượu etylic \(C_2H_5OH\)

Axit axetic \(CH_3COOH\)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1mol\)

\(2CH_3COOH+Na_2CO_3\rightarrow2CH_3COONa+H_2O+CO_2\uparrow\)

      0,2                  0,1                 0,2                  0,1         0,1

\(\%m_{CH_3COOH}=\dfrac{0,2\cdot60}{39,6}\cdot100\%=30,3\%\)      

\(\%m_{C_2H_5OH}=100\%-30,3\%=69,7\%\)

a)

\(n_{CO_2}=\dfrac{2,24}{22,4}=0,1\left(mol\right)\)

PTHH: 2CH₃COOH + Na₂CO₃ --> 2CH₃COONa + CO₂ + H₂O

                 0,2<----------0,1<-------------0,2<-------0,1

=> \(m_{CH_3COOH}=0,2.60=12\left(g\right)\)

\(\%m_{CH_3COOH}=\dfrac{12}{39,6}.100\%=30,3\%\)

\(\%m_{C_2H_5OH}=\dfrac{39,6-12}{39,6}.100\%=69,7\%\)

b) dd sau pư chứa \(\left\{{}\begin{matrix}CH_3COONa:0,2\left(mol\right)\\C_2H_5OH:\dfrac{39,6-12}{46}=0,6\left(mol\right)\end{matrix}\right.\)

\(V_{dd}=\dfrac{0,1}{2}=0,05\left(l\right)\)

=> \(\left\{{}\begin{matrix}C_{M\left(CH_3COONa\right)}=\dfrac{0,2}{0,05}=4M\\C_{M\left(C_2H_5OH\right)}=\dfrac{0,6}{0,05}=12M\end{matrix}\right.\)

\(n_{CO_2\left(đktc\right)}=\dfrac{10,64}{22,4}=0,475\left(mol\right)\\a, K_2CO_3+2CH_3COOH\rightarrow2CH_3COOK+CO_2+H_2O\\ b,n_{K_2CO_3}=n_{CO_2}=0,475\left(mol\right)\\ \Rightarrow m_{K_2CO_3}=138.0,475=65,55\left(g\right)\\ n_{CH_3COOH}=0,475.2=0,95\left(mol\right)\\ C\%_{ddCH_3COOH}=\dfrac{0,95.60}{200}.100=28,5\%\)

\(a,n_{\left(CH_3COO\right)_2Mg}=\dfrac{7,1}{142}=0,05\left(mol\right)\)

PTHH: \(Mg+2CH_3COOH\rightarrow\left(CH_3COO\right)_2Mg+H_2\uparrow\)

                        0,1<----------------0,05-------------->0,05

\(\rightarrow V_{H_2}=0,05.22,4=1,12\left(l\right)\\ b,C\%_{CH_3COOH}=\dfrac{0,1.60}{100}.100\%=6\%\)

\(c,n_{C_2H_5OH}=\dfrac{6,9}{46}=0,15\left(mol\right)\)

PTHH: \(CH_3COOH+C_2H_5OH\xrightarrow[H_2SO_{4\left(đặc\right)}]{t^o}CH_3COOC_2H_5+H_2O\)

bđ          0,1                 0,15

pư          0,1                 0,1

spư         0                     0,05                          0,1

\(\rightarrow m_{este}=0,1.80\%.88=7,04\left(g\right)\)